{"id":211,"date":"2019-12-02T06:43:11","date_gmt":"2019-12-02T06:43:11","guid":{"rendered":"http:\/\/sites.gtiit.edu.cn\/parkgroup\/?page_id=211"},"modified":"2025-12-08T17:12:33","modified_gmt":"2025-12-08T17:12:33","slug":"publications","status":"publish","type":"page","link":"https:\/\/sites.gtiit.edu.cn\/parkgroup\/publications\/","title":{"rendered":"Publications"},"content":{"rendered":"
\n
(51) NaHBEt3-Catalyzed 1,2-Hydroboration of a,b-Unsaturated Carbonyls: Mechanistic Insights into Hydride Transfer Pathways<\/span><\/div>\n<\/div>\n
\n

N. S. V. M. R.\u00a0Mangina, S. Park*<\/strong><\/p>\n

Synthesis\u00a02025\u00a0(accepted)<\/p>\n

(50) External ligand-free Pd-catalyzed 1,4-hydrosilylation of pyridines: mechanistic implication of dearomative remote hydride shift<\/p>\n

M. Shu,\u00a0S. Park*<\/strong><\/p>\n

Chem. Commun.\u00a02025 (accepted)<\/p>\n

(49) Ligand-Controlled Regiodivergent Double Hydroboration of Pyridines: A Catalytic Platform for the Synthesis of Diverse Functionalized Piperidines<\/p>\n

R.\u00a0Wang, S.\u00a0H.\u00a0Lee, X.\u00a0Huang, H.\u00a0Choi, D.\u00a0Kim, M.-H.\u00a0Baik*,\u00a0S.\u00a0Park*<\/b><\/p>\n

ACS Catal<\/i>.\u00a02025<\/b> (DOI:10.1021\/acscatal.5c04997)<\/p>\n<\/div>\n

(48) Recent Advances in Ligand-Controlled Regio- or Stereodivergent Transition Metal-Catalyzed Hydroelementation (E = H, B, Si, Ge) of C-C Unsaturated Systems<\/p>\n

Synthesis<\/em> 2024<\/strong>\u00a0(DOI: 10.1055\/a-2335-8516)<\/p>\n

(47) Selective Cascading Hydroboration of N-Heteroarenes via Cobalt Catalysis<\/p>\n

ACS Catal.<\/em>\u00a02024<\/strong>, 14<\/em>, 3582\u20133595<\/p>\n

(46) First-Row Transition Metal-Catalyzed Single Hydroelementation of N-Heteroarenes<\/p>\n

S. Park*<\/strong><\/p>\n

ChemCatChem<\/em>, e202301422<\/i>\u00a0(2023)<\/p>\n

(4<\/em>5<\/em>) Rhodium-Catalyzed Double Hydroboration of Quinolines<\/p>\n

R. Wang, S. Park*<\/strong><\/p>\n

ACS Catal<\/em>. 2023<\/strong>, 13<\/em>, 7067\u20137078.<\/p>\n

(44<\/em>) Rhodium-Catalyzed Double Hydroboration of Pyridine: The Origin of the Chemo- and Regioselectivities<\/p>\n

H. Choi, R. Wang, S. Kim, D. Kim, M.-H. Baik,* S. Park*<\/strong><\/p>\n

Catal. Sci. Technol.<\/em>\u00a02023<\/strong>,13<\/em>, 2735\u20132747.<\/p>\n

(43<\/em>)\u00a0Comparative DFT Study on Dehydrogenative C(sp)\u2212H Elementation (E = Si, Ge, and Sn) of Terminal Alkynes Catalyzed by a Cationic Ruthenium(II) Thiolate Complex<\/p>\n

L. Yahui, M. Zhou, S. Park,*<\/strong> and L. Dang*<\/p>\n

Inorg. Chem. <\/em>2021<\/strong>, 60, 6228-6238.<\/p>\n

(42<\/em>) Recent Advances in Metal-Catalyzed Asymmetric Hydroboration of Ketones<\/p>\n

R. Wang, S. Park*<\/strong><\/p>\n

ChemCatChem<\/em> 2021<\/strong>, 13, 1898-1919.<\/p>\n

(41<\/em>)\u00a0Recent advances in transition metal-free catalytic hydroelementation (E = B, Si, Ge, and Sn) of alkynes<\/p>\n

V. B. Saptal, R. Wang, S. Park*<\/strong><\/p>\n

RSC Adv.\u00a0<\/em>2020<\/strong>, 10<\/em>, 43539-43565.<\/p>\n

(40<\/em>) Light-mediated olefin coordination polymerization and photoswitches<\/p>\n

M. Li, R. Wang, M. S. Eisen, S. Park* <\/strong><\/p>\n

Org. Chem. Front.<\/em> 2020<\/strong>, 7<\/em>, 2088-2106.<\/p>\n

(39<\/em>) Recent Advances in Catalytic Dearomative Hydroboration of N-Heteroarenes<\/p>\n

S. Park*<\/strong><\/p>\n

ChemCatChem<\/em>\u00a02020<\/strong>, 12<\/em>, 3170-3185.<\/p>\n

(38<\/em>) Dual Reactivity of B(C6<\/sub>F5<\/sub>)3<\/sub> Enables the Silylative Cascade Conversion of N-Aryl Piperidines to Sila-N-Heterocycles: DFT Calculations<\/p>\n

M. Zhou, S. Park,*<\/strong> L. Dang*<\/p>\n

Org. Chem. Front.<\/em> 2020<\/strong>, 7<\/em>, 944-952.<\/p>\n

(37<\/em>) B(C6<\/sub>F5<\/sub>)3<\/sub>-Catalyzed sp3<\/sup> C-Si Bond Forming Cascade Reactions<\/p>\n

S. Park*<\/strong><\/p>\n

Chin. J. Chem.<\/em> 2019, <\/strong>37<\/em>, 1057-1071.<\/p>\n

(36<\/em>) Catalytic Reduction of Cyclic Ethers with Hydrosilanes<\/p>\n

S. Park*<\/strong><\/p>\n

Chem. Asian J.<\/em> 2019<\/strong>, 14<\/em>, 2048-2066.<\/p>\n

—————————————————————————————————Publications at GTIIT———————————————————————————————————-<\/p>\n

(35<\/em>) Double Hydroboration of Quinolines via Borane Catalysis: Diastereoselective One-Pot Synthesis of 3-Hydroxytetrahydroquinolines<\/p>\n

E. Kim, H. J. Jeon, S. Park<\/strong>,*<\/strong> S. Chang*<\/p>\n

Adv. Synth. Catal.<\/em> 2019<\/strong> (doi: adsc.201901050)<\/p>\n

(34<\/em>) Metal-Free Carbocyclization of Homoallylic Silyl Ethers Leading to Cyclopropanes and Cyclobutanes<\/p>\n

J. Zhang, C. K. Hazra, S. Park<\/strong>, S. Chang*<\/p>\n

Asian J. Org. Chem.<\/em> 2019<\/strong> (doi:10.1002\/ajoc.201900270)<\/p>\n

(33<\/em>) Alkoxide-Promoted Selective Hydroboration of N<\/em>-Heteroarenes: Pivotal Roles of in situ<\/em> Generated BH3<\/sub> in the Dearomatization Process<\/p>\n

E. Jeong, H. Heo, S. Park,*<\/strong> S. Chang*<\/strong><\/p>\n

Chem. Eur. J.<\/em> 2019<\/strong>, 25<\/em>, 6320-6325.<\/p>\n

(32<\/em>) Sequential C-H Borylation and N<\/em>-Demethylation of 1,1\u2019-Biphenylamines: An Alternative Route to Polycyclic BN-Heteroarenes<\/p>\n

J. Zhang, H. Jung, D.-W. Kim, S. Park,*<\/strong> and S. Chang*<\/p>\n

Angew. Chem. Int. Ed<\/em>. 2019<\/strong>, 58<\/em>, 7361-7365.<\/p>\n

(31<\/em>) Catalytic Access to Bridged Sila-N<\/em>-Heterocycles from Piperidines via Cascade sp3<\/sup> and sp2<\/sup> C-Si Bond Formation<\/p>\n

    \n
  1. Zhang, S. Park,*<\/strong> and S. Chang*<\/li>\n
  2. Am. Chem. Soc. <\/em>2018<\/strong>, 140<\/em>, 13209-13213 (Highlighted in JACS Spotlights, Chem-Station, and Synfacts<\/em>).<\/li>\n<\/ol>\n

    (30<\/em>) Piers\u2019 Borane-Mediated Hydrosilylation of Epoxides and Cyclic Ethers<\/p>\n

    J. Zhang, S. Park,*<\/strong> and S. Chang*<\/p>\n

    Chem. Commun. <\/em>2018<\/strong>, 54<\/em>, 7243-7246.<\/p>\n

    (29<\/em>) Silylative Reductive Amination of a,b-Unsaturated Aldehydes: A Convenient Synthetic Route to b-Silylated Secondary Amines<\/p>\n

    E. Kim, S. Park,*<\/strong> and S. Chang*<\/p>\n

    Chem. Eur. J.<\/em> 2018<\/strong>, 24<\/em>, 5765-5769.<\/p>\n

    (28<\/em>) Reductive Carbocyclization of Homoallylic Alcohols to syn<\/em>-Cyclobutanes via Boron-Catalyzed Dual Ring-Closing Pathway<\/p>\n

    C. K. Hazra, J. Jeong, H. Kim, M.-H. Baik,* S. Park,*<\/strong> and S. Chang*<\/p>\n

    Angew. Chem. Int. Ed<\/em>. 2018<\/strong>, 57, 2692-2696.<\/p>\n

    (27<\/em>) Selective C-O Bond Cleavage of Sugars with Hydrosilanes Catalyzed by Piers\u2019 Borane Generated In Situ<\/p>\n

    J. Zhang, S. Park,*<\/strong> and S. Chang*<\/p>\n

    Angew. Chem. Int. Ed<\/em>. 2017<\/strong>, 56, 13757-13761 (Highlighted in Organic Chemistry Portal).<\/p>\n

    (26<\/em>) Boron-Catalyzed Hydrogenative Reduction of Substituted Quinolines to Tetrahydroquinolines with Hydrosilanes<\/p>\n

    N. Gandhamsetty, S. Park<\/strong>,* and S. Chang*<\/p>\n

    Synlett<\/em> 2017<\/strong>, 28<\/em>, 2396-2400 (Highlighted in Organic Chemistry Portal<\/em>).<\/p>\n

    (25<\/em>) Catalytic Dearomatization of N<\/em>-Heteroarenes with Silicon and Boron Compounds<\/p>\n

    S. Park*<\/strong> and S. Chang*<\/p>\n

    Angew. Chem. Int. Ed. <\/em>2017<\/strong>, 56<\/em>, 7720-7738 + Angew. Chem.<\/em> 2017<\/strong>, 129<\/em>, 7828-7847.<\/p>\n

    (24<\/em>) Borane Catalyzed Ring Opening and Closing Cascades of Furans Leading to Silicon Functionalized Synthetic Intermediates<\/p>\n

    C. K. Hazra, N. Gandhamsetty, S. Park<\/strong>, and S. Chang*<\/p>\n

    Nat. Commun.<\/em> 2016<\/strong>, 7<\/em>, 13431 (Highlighted in Synform<\/em>).<\/p>\n

    (23<\/em>) Iridium-Catalyzed Selective 1,2-Hydrosilylation of N<\/em>-Heterocycles<\/p>\n

    J. Jeong, S. Park<\/strong>,* and S. Chang*<\/p>\n

    Chem. Sci.<\/em> 2016<\/strong>, 7<\/em>, 5362-5370.<\/em><\/p>\n

    (22<\/em>) Selective Silylative Reduction of Pyridines Leading to Structurally Diverse Azacyclic Compounds with the Formation of sp3<\/sup> C-Si Bonds<\/p>\n

    N. Gandhamsetty, S. Park<\/strong>,* and S. Chang*<\/p>\n

    J. Am. Chem. Soc. <\/em>2015<\/strong>, 137<\/em>, 15176-15184.<\/p>\n

    (21<\/em>) Boron-Catalyzed Silylative Reduction of Nitriles in Accessing Primary Amines and Imines<\/p>\n

    N. Gandhamsetty, J. Jeong, J. Park, S. Park<\/strong>, and S. Chang*<\/p>\n

    J. Org. Chem.<\/em> 2015<\/strong>, 80<\/em>, 7281-7287 (Highlighted in Organic Chemistry Portal<\/em>).<\/p>\n

    (20<\/em>) Chemoselective Silylative Reduction of Conjugated Nitriles under Metal-Free Catalytic Conditions Leading to \u03b2-Silyl Amines and Enamines<\/p>\n

    N. Gandhamsetty, J. Park, J. Jeong, S. W. Park, S. Park<\/strong>, and S. Chang*<\/p>\n

    Angew. Chem. Int. Ed.<\/em> 2015<\/strong>, 54<\/em>, 6832-6836 (Highlighted in Organic Chemistry Portal<\/em>).<\/p>\n

    (19<\/em>) Dual Role of Carboxylic Acid Additive: Mechanistic Studies and Implication for the Asymmetric C-H Amidation<\/p>\n

    D. Gwon, S. Park<\/strong>, and S. Chang*<\/p>\n

    Tetrahedron<\/em>, 2015<\/strong>, 71<\/em>, 4504-4511.<\/p>\n

    (18<\/em>) Boron-Catalyzed Silylative Reduction of Quinolines: Selective sp3<\/sup> C-Si Bond Formation<\/p>\n

    N. Gandhamsetty,\u2021<\/sup> S. Joung,\u2021<\/sup> S.-W. Park, S. Park<\/strong>,* and S. Chang*<\/p>\n

    J. Am. Chem. Soc. <\/em>2014<\/strong>, 136<\/em>, 16780-16783 (Highlighted in JACS Spotlights<\/em>).<\/em><\/p>\n

    (17<\/em>) Iridium(III)-Catalyzed C-H Amidation of Arylphosphoryls Leading to a P<\/em>-Stereogenic Center<\/p>\n

    D. Gwon, D. Lee, J. Kim, S. Park<\/strong>,* and S. Chang*<\/p>\n

    Chem. Eur. J.<\/em> 2014<\/strong>, 20<\/em>, 12421-12425 (Highlighted in Synfacts<\/em>).<\/p>\n

    (16<\/em>) Comparative Investigations of Cp*-Based Group 9 Metal-Catalyzed Direct C-H Amination of Benzamides<\/p>\n

    T. M. Figg,\u2021<\/sup> S. Park<\/strong>,\u2021<\/sup><\/strong> J. Park, S. Chang,* and D. G. Musaev* (\u2021<\/sup><\/strong>: equal contribution)<\/p>\n

    Organometallics<\/em> 2014<\/strong>, 33<\/em>, 4076-4085.<\/p>\n

    (15<\/em>) Selective Reduction of Carboxylic Acids to Aldehydes Catalyzed by B(C6<\/sub>F5<\/sub>)3<\/sub><\/p>\n

    D, Bezier, S. Park<\/strong>, and M. Brookhart<\/p>\n

    Org. Lett.<\/em> 2013<\/strong>, 15<\/em>, 496-499.<\/p>\n

    (14<\/em>) An Efficient Iridium Catalyst for Reduction of Carbon Dioxide to Methane with Trialkylsilanes<\/p>\n

    S. Park<\/strong>, D, Bezier, and M. Brookhart*<\/p>\n

    J. Am. Chem. Soc. <\/em>2012<\/strong>, 134<\/em>, 11404-11407.<\/em><\/p>\n

    (13<\/em>) Redistribution of Trialkyl Silanes Catalyzed by Iridium Silyl Complexes<\/p>\n

    S. Park<\/strong>, B. G. Kim, G\u00f6ttker-Schnetmann, I, and M. Brookhart*<\/p>\n

    ACS Catal. 2<\/strong><\/em>012<\/strong>, 2<\/em>, 307-316.<\/p>\n

    (12<\/em>) Development and Mechanistic Investigation of a Highly Efficient Ir(V) Silyl Complex for the Reduction of Tertiary Amides to Amines<\/p>\n

    S. Park<\/strong>, and M. Brookhart*<\/p>\n

    J. Am. Chem. Soc. <\/em>2012<\/strong>, 134<\/em>, 640-653.<\/p>\n

    (11<\/em>) Hydrosilylation of Epoxides with a Cationic h<\/em>1<\/sup>-Silane Iridium(III) Complex<\/p>\n

    S. Park<\/strong>, and M. Brookhart*<\/p>\n

    Chem. Commun. <\/em>2011<\/strong>, 47<\/em>, 3643-3645.<\/p>\n

    (10<\/em>) Hydrosilylation of Carbonyl-Containing Substrates Catalyzed by an Electrophilic h<\/em>1<\/sup>-Silane Iridium(III) Complex<\/p>\n

    S. Park<\/strong>, and M. Brookhart*<\/p>\n

    Organometallics <\/em>2010<\/strong>, 29<\/em>, 6057-6064.<\/p>\n

    (9<\/em>) Cyclopolymerization and Copolymerization of Functionalized 1,6-Heptadienes Catalyzed<\/p>\n

    by Pd Complexes: Mechanism and Application to Physical Gel Formation<\/p>\n

    S. Park<\/strong>, T. Okada, D. Takeuchi, and K. Osakada*<\/p>\n

    Chem. Eur. J. <\/em>2010<\/strong>, 16<\/em>, 8662-8678 (Cover Picture Paper<\/em>).<\/p>\n

    (8<\/em>) Cyclopolymerization of 9,9-Diallyl Fluorene Promoted by Ni Complexes: Stereoselective Formation of Six- and Five-Membered Rings during the Polymer Growth<\/p>\n

    D. Takeuchi, Y. Fukuda, S. Park<\/strong>, and K. Osakada*<\/p>\n

    Macromolecules<\/em> 2009<\/strong>, 42<\/em>, 5909-5912.<\/p>\n

    (7<\/em>) Controlled Cyclopolymerization of Dienes by Late Transition Metal Complexes<\/p>\n

    D. Takeuchi, S. Park<\/strong>, and K. Osakada*<\/p>\n

    J. Synth. Org. Chem., Jpn.<\/em> 2008<\/strong>, 66<\/em>, 1049.<\/p>\n

    (6<\/em>) Novel Precision Cyclopolymerization of Dienes by Late Transition Metal Catalysts<\/p>\n

    D. Takeuchi, S. Park<\/strong>, T. Okada, R. Matsuura, and K. Osakada*<\/p>\n

    Kobunshi Ronbunshu<\/em>, 2007<\/strong>, 64<\/em>, 597-606.<\/p>\n

    (5<\/em>) Cyclopolymerization of 1,6-Heptadienes Catalyzed by Iron and Cobalt Complexes: Synthesis of Polymers with Trans- or Cis-Fused 1,2-Cyclopentanediyl Groups Depending on the Catalyst<\/p>\n

    D. Takeuchi, R. Matsuura, S. Park<\/strong>, and K. Osakada*<\/p>\n

    J. Am. Chem. Soc.<\/em> 2007<\/strong>, 129<\/em>, 7002-7003.<\/p>\n

    (4<\/em>) Pd-Catalyzed Polymerization of Dienes that Involves Chain-Walking Isomerization of the Growing Polymer End: Synthesis of Polymers Composed of Polymethylene and Five-Membered-Ring Units<\/p>\n

    T. Okada, S. Park<\/strong>, D. Takeuchi, and K. Osakada*<\/p>\n

    Angew. Chem. Int. Ed.<\/em> 2007<\/strong>, 46<\/em>, 6141-6143 [Inside Cover Picture Paper<\/em>].<\/p>\n

    (3<\/em>) Pd Complex-Promoted Cyclopolymerization of Functionalized a,w-Dienes and Copolymerization with Ethylene to Afford Polymers with Cyclic Repeating Units<\/p>\n

    S. Park<\/strong>, D. Takeuchi, and K. Osakada*<\/p>\n

    J. Am. Chem. Soc.<\/em> 2006<\/strong>, 128<\/em>, 3510-3511.<\/p>\n

    (2<\/em>) Pd Complex-Promoted Cyclopolymerization of Diallylmalonates<\/p>\n

    S. Park<\/strong>, D. Takeuchi, and K. Osakada*<\/p>\n

    Studies in Surface Science and Catalysis <\/em>2006<\/strong>, 161<\/em>, 201-204.<\/p>\n

    (1<\/em>) Preparation of Human Epidermal Growth Factor\/Low-Molecular-Weight Chitosan Conjugates and Their Effect on the Proliferation of Human Dermal Fibroblasts in Vitro<\/em><\/p>\n

    T. I. Son*, S. Park<\/strong>, H. S. Kang, Y. S. Son, C. H. Kim, and E. Jang<\/p>\n

    J. Ind. Eng. Chem<\/em>. 2005<\/strong>, 11<\/em>, 34.<\/p>\n

    10. Invited lecture in University of Tsukuba and lunch photo with Prof. Kuwabara (September 22, 2023).<\/p>\n

    10. Invited lecture in University of Tsukuba and lunch photo with Prof. Kuwabara (September 22, 2023).<\/p>\n","protected":false},"excerpt":{"rendered":"

    (51) NaHBEt3-Catalyzed 1,2-Hydroboration of a,b-Unsaturated Carbonyls: Mechanistic Insights into Hydride Transfer Pathways N. S. V. M. R.\u00a0Mangina, S. Park* Synthesis\u00a02025\u00a0(accepted) (50) External ligand-free Pd-catalyzed 1,4-hydrosilylation of pyridines: mechanistic implication of dearomative remote hydride shift M. Shu,\u00a0S. Park* Chem. Commun.\u00a02025 (accepted)… Read More<\/a><\/p>\n","protected":false},"author":5,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"elementor_header_footer","meta":[],"_links":{"self":[{"href":"https:\/\/sites.gtiit.edu.cn\/parkgroup\/wp-json\/wp\/v2\/pages\/211"}],"collection":[{"href":"https:\/\/sites.gtiit.edu.cn\/parkgroup\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/sites.gtiit.edu.cn\/parkgroup\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/sites.gtiit.edu.cn\/parkgroup\/wp-json\/wp\/v2\/users\/5"}],"replies":[{"embeddable":true,"href":"https:\/\/sites.gtiit.edu.cn\/parkgroup\/wp-json\/wp\/v2\/comments?post=211"}],"version-history":[{"count":3,"href":"https:\/\/sites.gtiit.edu.cn\/parkgroup\/wp-json\/wp\/v2\/pages\/211\/revisions"}],"predecessor-version":[{"id":1238,"href":"https:\/\/sites.gtiit.edu.cn\/parkgroup\/wp-json\/wp\/v2\/pages\/211\/revisions\/1238"}],"wp:attachment":[{"href":"https:\/\/sites.gtiit.edu.cn\/parkgroup\/wp-json\/wp\/v2\/media?parent=211"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}